Chemistry of AlkaloidsDiscovery Publishing House, 2007 - 338 This book is written for B.Sc., B.Sc. (Hons.) and M.Sc., students. The subject is presented in a very systematic manner. Simple language is used, diagrams/ illustrations are generously used to emphasise reaction. Sites, to indicate reaction pathways. Emphasis is placed on the correlation of the structure of functional group with its properties. A detailed molecular orbital and valance bond interpretation of the structure of each functional group is given. This enable the student to predict the properties of the functional group. Fundamental principles of energetics, reaction rates and stereochemistry are provided to lay a strong foundation. Mechanisms are described in a step by step manner. Contents: Alkaloids, Stereochemistry of the Cinchona Alkaloids, Isoquinoline Group, Biosynthesis of Alkaloids. |
Spis treści
Alkaloids | 1 |
Stereochemistry of the Cinchona Alkaloids | 62 |
Stereochemistry of the Cinchona | 125 |
Isoquinoline Group | 243 |
Biosynthesis of Alkaloids | 325 |
Kluczowe wyrazy i wyrażenia
abietic acid absolute configuration acetate alcohol alkaloids androsterone angular methyl group anhydride axial Beckmann rearrangement benzene ring biosynthesis biphenyl bromine carbon atoms carboxyl group catalytic CH₂ CH₂OH chiral centres chloride cholesterol cinchonine CO₂H CO₂H CO₂H compound contains converted cyclic derivative double bond ecgonine enantiomers ephedrine equatorial ergocalciferol ergosterol ester follows formation formula gave geometrical isomerism gives H H H H₂C H₂O heated HO₂C hormones hydrogen atom hydrolysis hydroxide hydroxyl group hygrine iodide isolated isomer isomeric keto group ketone MeO MeO meroquinene method molecular molecule nicotine nitrogen atom NO₂ nucleus obtained occurs oestrone OH OH optically active ORD curve oxidation oxidised oxime phosphorus piperidine position potassium presence pyridine quinine racemisation reaction reduction resolved rotation rubber showed shown side-chain sodium solution spectrum stereochemistry steric steroids structure substituent sulphoxides sulphur tertiary trans tropine tropinone VIII X-ray analysis ОН