Thermodynamic and Kinetic Aspects of the Vitreous State

Przednia okładka
CRC Press, 14 gru 1994 - 224
This is the first book to logically present the major problems of the vitreous state within the framework of irreversible thermodynamics. Filled with elementary explanations for difficult problems, this easily understood text/reference treats in detail the criteria of glass transition, the peculiarities of relaxing structural parameters, and the Prigogine-Defay ratio. Based on the author's rigorous generalization of the Second Law for non-equilibrium, the book systematizes all known thermodynamic data for glasses and melts. The thermodynamic essence of structural relaxation and memory effects are considered. The viscous flow theories are treated as a constituent of the kinetic description. All theoretical questions are illustrated by comparison of calculations with the experiments for glasses of inorganic and organic nature, with special attention to structural classification. An informative review of modern structural investigations is included. The bibliography follows the history of the main problems from the nineteenth century.
 

Co mówią ludzie - Napisz recenzję

Nie znaleziono żadnych recenzji w standardowych lokalizacjach.

Spis treści

Introduction
1
E Thermodynamic Criteria for the Glass Transition
20
PrigogineDefay Ratio and the Problem of Structural
27
Thermodynamic Functions of Glasses
57
Changing of Thermodynamic Functions as a Result
83
Potential Energy and Interacting Particles Heat Energy
87
OrderDisorder Correlations in the Structure of Glass
101
Functions
107
Free Energy of Activation and Activation Entropy
154
The Volume of Activating Units
156
Free Energy of Activation and Particle Interaction Energy
160
Correlation Between Activation Entropy and Configurational Entropy
165
Theory of the Temperature Dependence of Viscosity
166
Comparison of the Theory with Experiment
171
Viscosity of Glasses with Frozen Structure
176
Concluding Remarks
179

Viscosity Theories of Glassforming Melts and Glasses
133
Bond Switching
153

Inne wydania - Wyświetl wszystko

Kluczowe wyrazy i wyrażenia

Popularne fragmenty

Strona 196 - Doolittle, AK (1951). Studies in Newtonian flow II. The dependence of the viscosity of liquids on free space.
Strona 185 - X-ray diffraction study of the structure of silicate glasses. Part 1. Alkali metasilicate glasses, Phys. Chem. Glasses, 24, 65 (1983).
Strona 193 - Anomalous changes in some properties of silica glass densified at very high pressures.

Odniesienia do tej książki

Informacje bibliograficzne