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Separation of Mixed Oxides. 1. Oxides containing Dysprosium, Holmium, and Yttrium, with Traces of Erbium, Terbium, and Neodymium.-These were dissolved in nitric acid, diluted to about 600 cc., boiled, and a solution of potassium cobalticyanide added until a quantity of precipitate had formed. This was filtered off and the process repeated. The precipitates were boiled with sodium hydroxide, filtered, washed, and dissolved in nitric acid. The solutions were then precipi. tated as the oxalates, ignited, and again converted into the nitrates, the solutions of which were examined by means of a spectroscope.

Fraction I. showed very strong holmium and dysprosium bands and traces of neodymium and erbium. In Fraction II. holmium and dysprosium were still very strong, neodymium was weak, and there was a trace of erbium. Fraction III. showed strong neodymium, dysprosium, and holmium bands. There was a slight trace of erbium. In Fraction IV. neodymium was stronger while holmium and dysprosium were weak. The material was mainly yttrium

nitrate.

Fraction I. was diluted, boiled, and more cobalticyanide added. The precipitate that formed was filtered off and the remaining rare earth thrown out as the oxalate. These

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The cobalticyanide method is excellent for the separation of yttrium from erbium and vice versa. The precipi. tates are very crystalline, and the process can be quickly carried out.

One of the authors and another are investigating the ferricyanides, which are nice crystalline compounds, and which differ very considerably in their solubilities. By fractionally precipitating a solution of the nitrates of yttrium and erbium with potassium ferricyanide, a rapid separation is effected.—Journal of the American Chemical Society, xxxviii., No. 8.

PROCEEDINGS OF SOCIETIES.

THE INSTITUTION OF PETROLEUM

TECHNOLOGISTS.

AT the Fourth Annual General Meeting of the Institution
the following elections were announced:-
President Mr. Charles Greenway.
Vice-President-Prof. John Cadman.

Honorary Members-Sir Frederick Black, C.B.; M-jor A. Cooper-Key, C.B.

Vice-Presidents-The Rt. Hon. Viscount Cowdray of Cowdray; Sir Thomas H. Holland, K.C.I.E., D.Sc., F.R.S.; Sir Boverton Redwood, Bart., D.Sc., F.R.S.E.

Council-Alfred C. Adams; Herbert Allen; Sir Robert Balfour, Bart., M.P.; Capt. R. W. Barnett, M.P.; Herbert Barringer, M. Inst.C.E., M.I.Mech. E., M.I.N.A.; Sir George Beilby, LL.D., F.R.S.; Edwin R. Blundstone, B.A., F.C.S.; Andrew Campbell; John T. Cargill; E. H. Cunningham Craig, B.A., F.R.S.E., F.G.S.; Arthur W. Eastlake, M. Inst. M.E., A.M.I. Mech. E.; T. C. Palmer, Assoc.M. Inst.C.E.; F. Mollwo Perkin, Ph.D., F.I.C., F.C.S.; Robert Redwood, F.C.S.

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2. Separation of Erbium from Yttrium.- The oxide used was very rich in erbium. Twenty-five grms. were dissolved in hydrochloric acid, diluted to about 800 cc., and precipi tated as in the case of the dysprosium, holmium, and yttrium oxides. Two fractions were taken, and these, after converting to oxides and re-dissolving, were again fractioned. Fraction I. gave Fractions III., IV., and V., while Fraction II. gave Fraction VI. and VII. The oxides varied from a rose-colour to an extremely pale pink. Frac tion III., the least soluble, possessed the most colour, and Fraction VII., the most soluble, was the palest.

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NOTICES OF BOOKS.

One Hundred Chemical Problems. By E. ARTHUR MASON, B.Sc. (Hons.). London: G. Bell and Sons, Ltd. 1917. Pp. 8. Price 6d. net.

THE chemica problems in this pamphlet are classified according to subjects and include numerical questions and calculations on molecular weights, the determination of equivalent and atomic weights, corrections for temperature and pressure, vapour density experiments, diffusion, and some miscellaneous problems. The questions are mostly of a straightforward type and are fairly easy, and the book will be useful for candidates for the University Local and other examinations who require some practice in chemical arithmetic.

Practical Sanitation. By GEORGE REID, M.D., D.P.H. Eighteenth Edition, Revised. London: Charles Griffin and Co., Ltd. 1916. Pp. xii+367. Price 6s. net. THIS book is known to all sanitary engineers and inspectors, and it is possibly quite unnecessary to call attention to its excellence, for all who are interested in the subject will be fully aware of it. It is undoubtedly the most authoritative and widely used text-book on sanitation in the English language, and is quite without a rival in its own line. The fact that this last edition is the eighteenth, issued twenty-five years after the first, is sufficient proof in itself that the book has been thoroughly appreciated. The last edition has been brought up to date, and some trifling alterations have been made, although the main plan is unaltered. The Appendix on Sanitary Law has been completely revised, and the matters dealt with in it are now included in the general index and are not indexed separately as before.

CHEMICAL NEWS,

April 20, 1917

Commercial Supply of Potash.

A Practical Manual of Autogenous Welding (Oxy
acetylene). By R. GRANJON and P. ROSEMBERG. Trans-
lated by D. RICHARDSON, Wh. Ex., A.M I.M.E. Fourth
Edition. London: Charles Griffin and Co., Ltd. 1916.
Pp. xxii +244. Price 5s. net.

The fourth edition of this most useful work has been
thoroughly revised and edited by the translator, and addi-
tional explanations are given of some parts which were
Many fresh illustra-
originally a little difficult to follow.
tions have been added, and new information which has
been accumulated since the publication of the third edition
in 1915. The book is a thoroughly practical guide for the
welder, who will be able to learn from it all the details of
his art, the best methods of manipulation, and the choice
of materials and apparatus.

A Text-book of Thermo-chemistry and Thermodynamics.
By Prof. OTTO SACKUR, Ph.D. Translated and Revised
London: Macmillan and
by G. E. GIBSON, Ph.D.
Co., Ltd. 1917. Pp. xvi+ 439. Price 12s. net.
THE essential facts of thermodynamics which must be
thoroughly understood before the student can hope to
obtain any real grasp of the principles of physical chemis-
try are very clearly explained in this book. The trans-
lator has made a good many alterations in the text and is
responsible for some important additions and new sections.
Thus, to mention a few changes, the discussion of the
theory of Debye is original, and also the whole of the
chapter on thermodynamic equilibrium in general, which
takes the place of the section on "Freie Energie und
Thermodynamisches Potential" in the German edition.
The section on the distribution of energy in the spectrum
has been entirely rewritten and is a very successful piece
of work. There is much to commend in the book, which
provides a very satisfactory course of thermodynamics for
the use of the advanced student. The explanations are
always concise and clear, and every effort has been made
to foresee difficulties and to throw light upon some matters
which students frequently find particularly puzzling. Heat
radiation and the Nernst heat theorem are very well
treated, and the numerical illustrations of important
formula and the worked out calculations are likely to
provide valuable aid in rendering the student's ideas clear
and definite.

Year Book of Pharmacy and Transactions of the British
Pharmaceutical Conference, 1916. London: J. and A.
Price to Non-members, 10s.
Churchill. Pp. 572.

was

THE Year Book of Pharmacy for 1916 contains detailed
reports of the Annual British Pharmaceutical Conference
held in London in July, at which an interesting Address
on the "Drug Resources of India and the Colonies"
delivered by the President, Dr. David Hooper, F.I.C. The
Year Book also contains abstracts of papers on scientific
subjects published from July, 1915, to June, 1916, in papers
and journals in all languages. They are classified under
chemistry, essential oils, materia
various headings
medica, new remedies, new apparatus, &c.-and are well
indexed. A list of subjects suggested for investigation is
also given, and the Executive Committee of the British
Pharmaceutical Conference hope that work will be under-
taken upon them. Some of the subjects have already been
appropriated, so that it is advisable that intending re-
searchers should communicate with the Secretary before
beginning work. A special fund exists to defray expenses
in connection with research work, and applications from
members of the Conference for grants will be considered
by the Executive Committee.

Although suitable for
| edition owed its great success.
students of college age and intellectual attainments, those
who had no previous knowledge of chemistry would quite
any who had studied the subject before would find that it
well be able to profit by its use, and it is safe to say that
cleared up many difficulties and hazy ideas in an
historical and philosophical aspects of the subject, and the
astonishing fashion. Special stress is laid upon the
student is well trained in clear precise thinking and the
"Chemical Views of Matter and Chemical Change and
careful use of appropriate words. The introduction on
Methods of Studying it," the chapters on Electro-motive
Chemistry," and on "Solutions," are particularly striking
ment in the second edition is the increased attention paid
examples of the author's lucid style, and one great improve-
to theoretical discussions. The questions at the ends of
the chapters will be found very helpful, as will also the
clear and full descriptions of methods of performing
calculations.

SIR

CORRESPONDENCE.

COMMERCIAL SUPPLY OF POTASH.

To the Editor of the Chemical News. us with the following information: The purpose of the present is to ask you to supply We foresee the possibility of exporting potash after the war, as the internal production greatly exceeds the local demand.

I. Is potash used in industrial concerns, and in which branch? The total quantity of potash used yearly, according to quality and destination (the requirements of various branches of industry).

2. Is the requirement of the said article satisfied exclusively by local production; exclusively by imported potash, both by local production and imported? Point out the relative importance on the market of American and Russian potash, mentioning the relation according to the duction and imported potash for the last year, mentioning various qualities. Statistics as to quantity of local prothe quantity for each quality separately, and in the case of imported goods also from which country. Data (for each and buckwheat, &c.) used in the country, both local proquality of aw produce, ashes, wood, stalks, sunflowers, duction and imported.

3. Prices and fluctuations of same on the local markets to quality. General remarks as to the local markets (each for the years 1913-1916, and the present prices according separately), relative position of demand and offers, tendencies for the decrease or increase of demand, &c., for the above period.

4. Conditions of import (cash c.i.f. er f.o.b. credit, names and addresses of banks speeially connected with the import of potash).

5. The comparative position of competition on the local potash market, as well as other potassium salts.

6. Addresses of local producers, importers, and exporters the local markets. I am, &c., V. SAVITZKY, General Secretary. of potash, list of largest firms abroad exporting potash on Russo-British Chamber of Commerce, 4, Gorochovaïa, Petrograd, March 6/19, 1917.

General Chemistry for Colleges. By ALEXANDER SMITH, THE DEVELOPMENT OF MINERAL RESOURCES.
Second Edition. London: G. Bell and Sons, Ltd.
1916. Pp. x+662. Price 6s. 6d. net.

THE second edition of this book has been practically re-
written, so that it may be regarded as a new work posses-
ing, however, all the excellent features to which the earlier

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To the Editor of the Chemical News. SIR,-With reference to Mr. Giles's letter I am in hearty agreement with his suggestion as to deep borings, and carried on as a State enterprise. I am sure if some central

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authority was established where information which is at present available could be collected, tabulated, and to some extent corroborated, we should then find what hitherto little known valuable deposits of minerals exist in the British Isles. I have myself found cobalt ore associated with the hematite and limestone deposits of the mountains in the neighbourhood of Dyserth, North Wales, and am sure most readers can point to some deposits probably in their own locality containing the rarer metals but at the present time undeveloped owing to lack of individual enterprise. I am, &c.

Shotton, Chester, April 14, 1917.

H. PROCTER SMITH, F.C.S.

CHEMICAL NOTICES FROM FOREIGN SOURCES.

Nor. All degrees of temperature are Centigrade unless otherwise expressed.

Bulletin de la Société Chimique de France.
Vol. xxi.-xxii., No. 1, 1917.

Method of Formation of 6.6-Dichloro-2. 2-azobenzoic Acid.-S. Reich and W. Merki.-The authors have found that when hydrocyanic acid acts upon 6-chloro2-nitrobenzoic aldehyde, and the cyanhydrine obtained is saponified, 6.6-dichloro-2.2-azobenzoic acid is obtained in the form of yellow crystalline needles. This acid behaves curiously when reduced; stannous chloride or hydrogen in presence of palladium transforms it into a substance insoluble in alkalis and acids and having the empirical formulæ C14H6O2N2C|1⁄2.

Total Synthesis of Santene.-Gust. Komppa and S. V. Hintikka. - The authors have already shown that camphenilone can be transformed into isocamphenilone by first reducing it and then acting on the alcohol thus obtained with phosphorus pentachloride. When HCl is removed from the chloride of camphenilyl a hydrocarbon is obtained, namely, camphenilene, and this gives the acetate of isocamphenilyl on treatment with sulphuric acid mixed with acetic acid. On saponification isocamphenilol is formed and isocamphenilone by oxidation. It has now been found that the hydrocarbon is not a single substance, but is a mixture containing santene, while the isocamphenilolol is identical with santenol and the isocamphenilone with santenone.

second Course is to be held during the Spring and Summer on Wednesdays, at 4 p.m., in the Lecture Room of the Institute, 37, Russell Square, W.C. 1. The lectures are being delivered by distinguished experts, and each discussion is to be presided over by a well-known public leader. The following condensed version of the programme indicates the representative character of the course:

April 18." Mental States and the War," by Sir Robert Armstrong Jones, M.D., F.R.C.P.

April 25.-"Citzenship and Health Questions in War Time," by Dr. Chas. Porter.

May 2.-Imperial Health and the Dysgenics of War," by C. W. Saleeby, M.D., F.R.S.Ed.

May 9.

"The Pathology of Venereal Disease," by Major F. W. Mott, M.D., F.R.S., F.R.C.P. May 16." Public Health and the Control of the Liquor Traffic," by The Rt. Hon. Lord D'Abernon. May 23." The Re-education and Training of Disabled Combatants," by Sir C. Arthur Pearson, Bart. May 30. Health and Insect Life in War and Peace," by Dr. A. E. Shipley, F.R.S.

June 6.-"Welfare Work in Factories," by B. Seebohm Rowntree.

June 13.-"The Management of Neurasthenia and Allied Disorders in the Army," by Hon. and Temp. Lt. Col. Sir John Collie, M.D.

June 20.-" Food Production in Peace and War," by Dr. E. J. Russell, F.R.S.

June__27." The Value and Importance of Physical Exercises from a National Standpoint," by Sir William Milligan, M.D.

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MISCELLANEOUS.

Co-operation and Research Work.-Recent enterprises in connection with the preparation of food and the development of its concessions in West Africa and elsewhere, have led to the establishment of a Research Department by the Co-operative Wholesale Society, and Dr. Geoffrey Martin, M.Sc. (Bristol), B.Sc. (Lond.), has just been appointed to direct its work. Dr. Martin is a well-known chemist and the author of several standard works on the application of science to industry. appointment marks a new departure in connection with the co-operative movement, and has been rendered necessary by the concessions acquired by the Co-operative Wholesale Society in West Africa, Nigeria, and elsewhere, as well as by the development of fresh undertakings at home.

This

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A TEXT-BOOK OF THERMO-CHEMISTRY AND THERMODYNAMICS.

By Professor OTTO SACKUR, Ph.D. Translated and Revised by G. E. GIBSON, Ph.D., Instructor in Chemistry in the University of California. 8vo. 12s. net.

THE ATHEN.EUM. As a work dealing especially with the relations of thermo-dynamics and physical chemistry, this book should be of considerable value for reference and study." NEW EDITION JUST PUBLISHED. THEORETICAL CHEMISTRY FROM THE STANDPOINT OF AVOGADRO'S RULE AND THERMO-DYNAMICS.

By Professor WALTER NERNST, Ph.D. New Edition, Revised by H. T. TIZARD, M.A. 8vo. 15s net.

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THE

ALCHEMICAL

SOCIETY

was formed in 1912 for the study of the early history of Chemistry and the works and
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The Annual Subscription to the Society is 12s. 6d. Members receive the Journal gratis, and those desirous of doing so, may receive Les Nouveaux Horizons, the official publication of La Société Alchimique de France, free of charge, except postage (6d. per annum).

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