Polyoxometalate Molecular Science

Przednia okładka
Juan J. Borrás-Almenar, E. Coronado, Achim Müller, Michael Pope
Springer Science & Business Media, 31 gru 2003 - 475

Polyoxometalates (POMs) form a large, distinctive class of molecular inorganic compounds of unrivaled electronic versatility and structural variation, with impacts ranging from chemistry, catalysis, and materials science to biology, and medicine. This book covers the basic principles governing the structure, bonding and reactivity of these metal-oxygen cluster anions and the major developments in their molecular science.

The book comprises three sections. The first covers areas ranging from topological principles via synthesis and stability to reactivity in solution. It also focuses on the physical methods currently used to extract information on the molecular and electronic structures as well as the physical properties of these clusters. The second part reviews different types of POMs, focusing on those systems that currently impact other areas of interest, such as supramolecular chemistry, nanochemistry and molecular magnetism. The third section is devoted to POM-based materials and their applications and prospects in catalysis and materials science.

 

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Spis treści

INTRODUCTION TO POLYOXOMETALATE CHEMISTRY
3
GENERAL PRINCIPLES OF THE SYNTHESIS OF POLYOXOMETALATES IN AQUEOUS SOLUTION
33
GENERAL STRATEGIES FOR NONAQUEOUS POLYOXOMETALATE SYNTHESIS
55
STRUCTURE AND BONDING IN HIGHVALENT EARLY TRANSITION METAL COMPOUNDS
79
EXTENDED HUCKEL MOLECULAR ORBITAL CALCULATIONS AND SPECTROSCOPIC PROPERTIES
175
FORMATION OF PARAMAGNETICSPECIES PAIR BY TRIPLET MECHANISM
211
FUNCTIONALIZED POLYOXOMETALATES
233
SULFURCONTAINING KEGGIN ANIONS AND CYCLIC POLYOXOTHIOAMONS
253
PERSPECTIVES FOR NANO SUPRAMOLECULAR AND SOLIDSTATE CHEMISTRY
297
APPLICATIONS OF POLYOXOMETALATES IN HOMOGENEOUS CATALYSIS
327
HETEROGENEOUS CATALYSIS BY HETEROPOLY COMPOUNDS
351
PHOTOCHEMISTRY AND PHOTOCATALYSIS BY POLYOXOMETALATES
381
HYBRID MATERIALS BASED ON POLYOXOMETALATES WITH SOLID STATE PROPERTIES
417
FROM STRUCTURE TO FUNCTION
441
Index
467
List of Contributors
473

MAGNETIC POLYOXOMETALATES
273

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