Polyoxometalate Molecular ScienceJuan J. Borrás-Almenar, E. Coronado, Achim Müller, Michael Pope Springer Science & Business Media, 31 gru 2003 - 475 Polyoxometalates (POMs) form a large, distinctive class of molecular inorganic compounds of unrivaled electronic versatility and structural variation, with impacts ranging from chemistry, catalysis, and materials science to biology, and medicine. This book covers the basic principles governing the structure, bonding and reactivity of these metal-oxygen cluster anions and the major developments in their molecular science. The book comprises three sections. The first covers areas ranging from topological principles via synthesis and stability to reactivity in solution. It also focuses on the physical methods currently used to extract information on the molecular and electronic structures as well as the physical properties of these clusters. The second part reviews different types of POMs, focusing on those systems that currently impact other areas of interest, such as supramolecular chemistry, nanochemistry and molecular magnetism. The third section is devoted to POM-based materials and their applications and prospects in catalysis and materials science. |
Spis treści
3 | |
GENERAL PRINCIPLES OF THE SYNTHESIS OF POLYOXOMETALATES IN AQUEOUS SOLUTION | 33 |
GENERAL STRATEGIES FOR NONAQUEOUS POLYOXOMETALATE SYNTHESIS | 55 |
STRUCTURE AND BONDING IN HIGHVALENT EARLY TRANSITION METAL COMPOUNDS | 79 |
EXTENDED HUCKEL MOLECULAR ORBITAL CALCULATIONS AND SPECTROSCOPIC PROPERTIES | 175 |
FORMATION OF PARAMAGNETICSPECIES PAIR BY TRIPLET MECHANISM | 211 |
FUNCTIONALIZED POLYOXOMETALATES | 233 |
SULFURCONTAINING KEGGIN ANIONS AND CYCLIC POLYOXOTHIOAMONS | 253 |
PERSPECTIVES FOR NANO SUPRAMOLECULAR AND SOLIDSTATE CHEMISTRY | 297 |
APPLICATIONS OF POLYOXOMETALATES IN HOMOGENEOUS CATALYSIS | 327 |
HETEROGENEOUS CATALYSIS BY HETEROPOLY COMPOUNDS | 351 |
PHOTOCHEMISTRY AND PHOTOCATALYSIS BY POLYOXOMETALATES | 381 |
HYBRID MATERIALS BASED ON POLYOXOMETALATES WITH SOLID STATE PROPERTIES | 417 |
FROM STRUCTURE TO FUNCTION | 441 |
467 | |
List of Contributors | 473 |
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Polyoxometalate Molecular Science Juan J. Borrás-Almenar,E. Coronado,Achim Müller,M.T. Pope Ograniczony podgląd - 2012 |