reply to Mr. Irwin, the author said that the small deflexion due to magnetic impurities in the moving coil could be eliminated in all balance tests by using a false zero method. In deflexional methods the effect could be rendered negligible by reducing the voltage exciting the field, and using a moving coil current of correspondingly increased strength. Mr. PHILLIPS stated that the present paper was preliminary to a more detailed account of the work which had been done with the instrument. In reply to Mr. Irwin, he stated that it was proposed to make use of the instrument to measure the Specific Inductive capacity of materials and the resistance of electrolytes. Mr. A. E. GARRETT read a paper entitled "Positive Electrification due to Heating Aluminium Phosphate." In 1904 Dr. R. S. Willows and the author communicated to this Society the results of some experiments on the halogen compounds of zinc, in which it was shown that those compounds when heated ionised the air around so that both positively and negatively electrified bodies gradually lost their charge. Work in this direction was continued, and the results obtained showed that a large number of inorganic compounds possess properties of a like nature to the above. In 1907 Sir J. J. Thomson found that chlorides, phosphates, and nitrates give off an excess of positive ions when heated, and he incidentally discovered that aluminium phosphate was most active in this direction. As many of the substances previously examined are known to be unstable (and hence the ionisation produced may be the result of chemical change), while aluminium phosphate, on the other hand, is a most stable substance, it was thought that an investigation of the ion producing properties of that compound would be of interest. The apparatus was arranged so that the salt could be heated to the desired temperature (900-1300° C.) on a strip of platinum foil. The pressure could be reduced as required. For most of the experiments a sensitive galvanometer was used as recording instrument. With the usual distance between the electrodes (0.5 cm.) it was found that a difference of potential of 60 volts was sufficient to obtain a saturation current with the positive ions. The way in which the current varied with the time when the saturation voltage was applied was first investigated. For the first half-hour the current was somewhat irregular. This was found to be due to the water present in the salt. The current for the first hour or two appears to be largely influenced by the surrounding gas. Neglecting the preliminary effects due to water, the decay of the current with the time can be represented by a curve having the general formula A(e-1-e-2)+B(1-e-λst). The current finally obtained depends almost entirely upon the salt itself. After five or six hours' heating, no further change takes place in the current obtained under fixed conditions of temperature and pressure. A temporary increase, however, can be brought about by moistening the salt, and also by passing a discharge from an induction-coil through the tube for about half a minute. When the salt is insulated and heated for some time, an extraordinarily large current passes when the field is first put on. This effect increases with the time up to about ten minutes, after which any longer insulation causes no increase of the initial current. With the salt in the final steady state the conditions were suitable for experiments on temperature and pressure effects. It was found that for every temperature tried there was a certain pressure at which the current obtained was a maximum, and the higher the temperature the lower was this pressure. The currents obtained with constant pressure and variable temperature indicate that the relationship between the rate of production of positive ions and the absolute temperature can be represented by the Richardson formula Q ale 20. By using a quadrant electrometer in place of the galvanometer, it was found at pressures of o'o1 mm. that some positive ions are ejected with a velocity of the | order 106 cm. per sec.; and other experiments showed that the ions at very low pressures and acted upon by small electrostatic fields moved with great velocity, so it was thought that this substance could be made use of as a means for rectifying alternate currents. It was found that it could be so used. The values of l/m obtained by Thomson's cycloid method indicate that the smallest of the positive ions present possess a mass comparable with that of the hydrogen atom. Many of the results obtained, in particular (a) those with varying pressures and constant temperatures, (b) those at atmospheric pressure in which after removal of all free ions by a field sufficient to produce a saturation current, a current of equal values for ions of both signs was found at an electrode placed behind that on which the saturation voltage acted, and (c) the loss of charge of a Faraday cylinder when screened from the action of free ions, indicate that one of the products due to heating aluminium phosphate is in the form of neutral pairs or doublets which afterwards split up into negative and positive ions. NOTICES OF BOOKS. A Re-calculation of the Atomic Weights. By FRANK WIGGLESWORTH CLARKE, LL.D., D.Sc. Third Edition, Revised and Enlarged. City of Washington: Published by the Smithsonian Institute. 1910. THIS book contains a critical survey of all the information which has been accumulated with regard to atomic weights, special attention being paid to recent work. All data have been reduced to a common standard, and for each series of experiments the probable error is worked out by the usual formula. Then the mean is taken, and its probable error is also worked out. The fundamental ratios are first treated, and from them are deduced the highly probable values, based upon the most reliable evidence, of the atomic weights of ten elements. These values are then used for calculating the atomic weights of each of the other elements in turn. Even the comparatively meagre information to be found on the atomic weights of the rare earths is carefully tabulated, and the book is a valuable addition to chemical literature; it may be regarded as a standard authority on the subject of the atomic weights of the elements. Qualitative Analysis Tables for Use at the Bench. By E. J. LEWIS, B.A. (Cantab.), B.Sc. (Lond.), Assistant Master at Oundle School. Cambridge University Press. THESE tables are printed on stout card edged with metal, and are held together by two rings passing through eyelet holes in such a manner that they can be turned over quickly and easily as the work of analysis proceeds, and they will stand unsupported on the bench at an angle most convenient for reading. The main directions are printed in red rink and stand out well from the black text, and copious notes are given in italics; the foundations of analysis are discussed as fully as the limited space will allow. The use of these tables is restricted to the working bench, for they are too large to be carried about; they will doubtless be found useful where a number of students are working together through a course of chemistry. MISCELLANEOUS. Society for Extending the Rothamsted Experiments.-A meeting of the Society was held at Rothamsted on June 16th under the Presidency of the Duke of Devonshire. The Society has been incorporated with the object of obtaining additional funds for the development of the agricultural investigations which have been carried on so long under the late Sir John Lawes and the Lawes Agri The imme cultural Trust, which he afterwards founded. diate object of the Society is to obtain a sum of £5000 in order to secure about 200 acres of land adjoining the present experimental fields, and erect thereon the buildings required for feeding experiments with the crops under investigation. An appeal for subscriptions towards thus securing a small self-contained farm for the Rothamsted Experimental Station is now being circulated, and at the meeting of the Society on Thursday a first list of donations was reported from the Duke of Devonshire, Lord Iveagh, Sir J. T. Brunner, Colonel E. H. Carlisle, M.P., Mr. J. F. Mason, M.P., and Mr. J. Martin White, amounting to £1450. Drawing Office Accessories.-Messrs. Wm. J. Brooks and Co., Letchworth, Herts., have recently introduced several novelties to aid in the preparation of drawing diagrams, &c. Among the most useful are a number of mathematical curves accurately cut and engraved, in transparent celluloid : PARABOLA Eqn. y = x2; unit 1 inch. Axis, focus, and latus rectum marked. HYPERBOLA (Rectangular): Eqn. xy=1 inch. Axis marked. ELLIPSE Major axis 3 inches, minor axis 2 inches. Axes and foci marked. CYCLOID: Roulette of circle 2 inches diameter. Central ordinate marked. CUBIC Curve: Eqn. y=x3; unit I inch. Of these perhaps the parabola is the most useful; with its aid and a sheet of squared paper, square and square roots and other equations can be solved rapidly and with considerable accuracy. For the construction of curves thin flexible steel bands are provided. A simple form with small brass tabs at intervals of about 2 inches enables a curve to be set out and held in position by the fingers of one hand while the line is traced with a pencil. Another more elaborate device consists in a steel band connected to a number of stiffly moving brass links; with this instrument any curve or curves can be given to the steel band and retained by it while the line is being traced. These are made in various lengths. Another ingenious device is sold under the name of "Pinro"; it is an improvement on the common drawing-pin, and consists in a very thin flexible strip of brass with pin points placed every four inches; it is sold in lengths of twelve feet, and will be found useful for a variety of purposes besides the general use of a drawing-pin, and it has the great advantage that it does not roll on to the floor and get lost. NOTES AND QUERIES. Our Notes and Queries column was opened for the purpose of giving and obtaining information likely to be of use to our readers generally. We cannot undertake to let this column be the means of transmitting merely private information, or such trade notices as should legitimately come in the advertisement columns. Castor Seed.-Can any reader inform me if there is a test for the poisonous castor seed in cotton or cattle feeding cake ?-C. S. MEETINGS FOR THE WEEK. THURSDAY, 30th.-Royal Society. "New Method for the Quantitative Estimation of Hydrocyanic Acid in Vegetable and Animal Tissues," by Dr. A. D. Waller. "Comparative Toxicity of Theobromine and Caffeine as measured by their Direct Effect upon the Contractility of Isolated Muscle," by Drs. V. H. Veley and A. D. Waller. "Mubinyo, a Disease of Natives in Uganda" and "The Natural Food of Glossina palpalis," by Colonel Sir David Bruce and others. "Relation of Light Perception to Colour Perception," by Dr. F. W. Edridge-Green. "Anatomy and Morphology of the Leaves and Inflorescences of Werts hi mirabilis," by Miss M. G. Sykes. "Relative Atomic Weights of Nitrogen and Sulphur," by F. P. Burt and F. L. Usher. MACMILLAN'S NEW and RECENT BOOKS ON CHEMISTRY. Methods Used in the Ex amination of Milk and Dairy Products. By Dr. CHR. BARTHEL. Translation by W. GOODWIN, M.Sc., Ph.D., South-Eastern Agricultural College, Wye, Kent. Illustrated. 8vo. 7s. 6d. net. Theoretical Principles of the Methods of Analytical Chemistry based upon Chemical Reactions. By Professor M. G. CHESNEAU. Authorised Translation by Professor A. T. LINCOLN, Ph.D., and Professor D. H. CARNAHAN, Ph.D. 8vo. 7s. 6d. net. Practical Chemistry. By JAMES BRUCE, Ph.D., B.Sc., F.I.C., A.R.C.S., and HARRY HARPER, A.R.C.S., Head of the Chemistry Department of the Trade and Grammar School, Keighley. Globe 8vo. 2s. 6d. EDUCATIONAL NEWS.-"We have pleasure in recommending this book not only to students but to teachers of chemistry, and feel certain it will occupy a high place amongstebooks on like subjects." Crystalline Structure and Chemical Constitution. By A. E. H. TUTTON, M.A., D.Sc. (Oxon.), F.R.S., A.R.C.Sc. (Lond.). 8vo. 5s. net. [Science Monographs. NATURE." It is a goodly story that he has to tell, and well is it told; without wearying the reader with an unwieldy mass of details, he presents in all essential completeness a vivid picture of an unusually coherent series of investigations. The book is one that should be read and studied by all interested in crystals, their properties and their formation." FOURTH EDITION, entirely Re-written and Enlarged. Chemical Technology and Analysis of Oils, Fats, and Waxes. NATURE.—“Well maintains its place in the front rank of works devoted to the study of oils, fats, and waxes. To the chemical technologist it is practically indispensable." INDEX. BEL heat test for gun-cotton | Acids, resolution of externally AB and nitroglycerin, 68 of colour by reduction of Absorption and ionisation, rela- tion between, 1c3 of paratoluidine and meta- Acetylene tetrabromide and acety. of nitroso-derivatives of, 143 asaronic, 296 boric, effects of chlorides on camphorcarboxylic, and deriva- synthesis of, 213 284 a-cyclogeranic, 204 dextro-tartaric, method for de- dithionic, determination of, 48 for spheric oxidation of turpen- standard solutions, 180 hypoiodous, action of nascent, on unsaturated acids, 156 malonanilic, halogen deriva- reaction for, 251 A1-aonylenic, 79 perchloric, preparation sodium perchlorate, 42 picric, 228 sabinic, 251 from salicylic, estimation by distilla- sulphosalicylic, action on tri- chlorate on concentrated, 282 solution of platinum in, 107 compensated, 250 aromatic, catalysis of, 215 B-bromo-3-phenylpropionic, 66 cinnamic, absorption spectra of, dicarboxylic, action of bases on phenyltriazoacetic, substituted, 65 phosphinic, transformation of benzylethylpropylsilicane, 65 volatile, in wines and vinegars, apparatus for use in deter- Actinium B-rays of, ionisation of Africa, South, chemistry of veget- nitrates and oxides obtained by of lauric and n-nonoic acids Alcohol, absolute, as reducing specific gravity of, 275 tion into phosphinic acids by new method of detecting traces Alkaline earths. method of restor- potassium permanganate as test Alkyl halides and metals of iron tives, 221 Allen, E. T., and J. Johnston, stituents, determination, 9t nitrates and oxides obtained by tion due to heating, 299 molecular complexity in the 220 Amines, aromatic, action on ethyl and J. H. Coste. (See Coste, Anhydrides, action of gaseous carbon tetrachloride on, 108 Animal substances, skotographic and electroscopic effects of, 21 Anthocyan, 218 tri-, tetra-, and pentavalent, 95 fat extraction, 226 for demonstrating electrolysis of Balance, magnetic, of M. Curie and H. H. Dale, third active Barium hydrosulphate, 227 adsorption of uranium X by, 66 intramolecular rearrangemert salicylic acid on trisodic phos- Bartlett, E. H., and A. H. Gill. (See Gill, A. H.) Bases, resolution of externally coyne, "Chemical Conver- light upon silver sulphite and (See Bauriedel, F. and A. Gutbier. (See Gutbier, A.) vision of atomic weight of Beard, S. H., and J. J. Sud- Becker, W., dizinc-formaldehyde- Becquerel, H. and J., and H. K. Onnes, phosphorescence o Benzidine derivatives, acetylation, Benzoylhydrazobenzene, reduc- tion of nitroso-derivatives of, 204 mercaptan, reactions of, 297 Bergmann, L., and M. Le Blanc. view of the nature of chlorine, 37 vicianose, new reducing sugar chloride of phosphorus, 107 Bevan, P. V., absorption spectra Biddlecombe, A., "Thoughts on Natural Philosophy and the for rapid determination of re- W. T. Hall, and J. W. Phelan, 121 Blanc, G. L., and J. F. Thorpe, Komppa's synthesis of cam- Blich eldt, S. H., proposed me- thod for estimation of butter Bloch, L., phosphorescence and Bonnerot, S., and G. Charpy. Generation and Use," 215 12 'Ammonia and Coal-tar," 70 servation of Mass in," 46 of," 94 "Chemistry, History of," 82 duction to Experimental," 83 trical Engineers," 94 Chemical Constitution," 60 39 Books, Reviews and Notices of- | Bottles, gas-washing, with slight "Frick's (Dr. F.) Physical 91 "Immortality, Science and of Technology, Man - loidal Chemistry of," 107 "Manures and Soils," 203 and the tions, Conservation of," 46 Origin of Life, Thoughts "Steel Structures, Paints for," "Sugar, Beet-, Making, and its "Technische Auskunft," 107 " Van Nostrand's Chemical Annual," 22 222 Borck, H., and L. Moeser. (See Boron, crystalised, 167 chloride, reduction by hydrogen under action of electric dis- "Modern Bleaching Bougault, J., action of nascent Lowry, liquid water a ternary Bowser, L. T., speedy detection thermometric standards, 290 chemical reactions in gases Brochet, A., and A. Haller. (See Bromination with aqueous hypo- 201 substitution for chlorine in W. J. and Co, drawing office Brown, H. T, role of diffusion in J. A, estimation of small quan- Kjeldahl estimation of nitrogen N., rate of emission of a- in be- tween absorption and phos- of Radiology and Electricity, and our German cousins, 47 molecular weight of in latex, 35 at high temperatures, 125 estimation in iron and steel and solid, cementation of iron by, dioxide, burette for estimation influence of non-electrolytes on reduction of iron oxide by, 96 on anhydrides and oxides, 108 tallisation and true percarbon- Carboys, method of emptying, Carpaine, constitution, 125 cylic acid by distillation of its 227 Cereals, moisture determination earths, substitution of bro- organic derivatives of silicon, Chaney, N. K., and F. D. Chatt- away. (See Chattaway, F. D.) MacMahon, interaction of cementation of iron by solid 37 73 79 and F. A. Mason, halogen de- and J. M. D. Olmsted, action of Chelsea, South-Western Poly- technic Institute, 84, 132 address to the King, 282 report of Council, 210 Chlorine dioxide, inhibitive effect | Cornacea stolonifera, fruit of, 217 92 Chemistry, tinctorial, ancient and Colour extinction by reduction of Chemists, research, 75 Chesneau, G., analysis of niobites effects on solubility of boric acid, Chlorine absorption apparatus, 77 221 atomic weight, 264 Berthollet's view of nature of, 37 201 substitution of bromine and luminosity, 63 Colloids, influence on solubility of present state and its future, necessity of confirming reac- stability of B-ketoaldehydes, 216 Crossley, A. W., and C. Gilling, and Gertrude H. Wren, 3:5- 67 Croze, F., prolongation of ban spectrum of nitrogen in ex- Crystals of silver sulphate and di- Crystalline products of hydration DALE, H. H., and G. Barger. Danaila, M., synthesis of 5.7.5'7'- oxidation of dimethylaniline Darmois, E., artificial camphor, Darwin centenary celebration, 82 tion of quinolinic and aromatic new method of synthesising un- new method of estimating chlor- |